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Atomistry » Palladium » Chemical Properties » Potassium Thio-palladite | ||
Atomistry » Palladium » Chemical Properties » Potassium Thio-palladite » |
Potassium Thio-palladite, K2Pd3S4
Potassium Thio-palladite, K2Pd3S4, is obtained as hexagonal needles on heating to redness a mixture of 1 part of palladous sulphide with 12 parts of a mixture containing caustic potash and sulphur in equal proportions. Extraction of the melt with water leaves a residue of crystalline thio-palladite. The crystals are insoluble in water, violet-blue in colour when moist, but metallic grey when dry. They dissolve, with decomposition, in hydrochloric acid.
The aqueous solution of potassium thio-palladite interacts with one of silver nitrate to yield insoluble hexagonal lamellae of Silver Тhio-palladite, Ag2Pd3S4. |
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