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Atomistry » Palladium » Chemical Properties » Pentachlor-palladates | ||
Atomistry » Palladium » Chemical Properties » Pentachlor-palladates » |
Pentachlor-palladates, M2PdCl6
When the sesquioxide, Pd2O3.xH2O, is suspended in ether in the presence of rubidium chloride at the temperature of ether and solid carbon dioxide, small greyish green crystals of the double salt, Rubidium Pentachlor-palladate, 2RbCl.PdCl3 or Rb2PdCl5, are obtained. Caesium yields an analogous salt, Cs2PdCl5, in the form of dark green crystals.
Both salts decompose in contact with water, the corresponding tetrachlor-palladites, Rb2PdCl4 and Cs2PdCl4 respectively, being obtained. Potassium chloride, in similar circumstances, does not yield a pentachlor-palladate, but only the tetrachlor-palladite, K2PdCl4, and the double salt, PdCl2.4KCl. |
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